(−)-Istanbulin A
نویسندگان
چکیده
THE TITLE COMPOUND (SYSTEMATIC NAME 9a-hydr-oxy-3,4a,5-trimethyl-4a,6,7,8a,9,9a-hexa-hydro-4H,5H-naphtho[2,3-b]furan-2,8-dione), C(15)H(20)O(4), is a sesquiterpene lactone showing the typical eremophilanolide skeleton, which has been isolated from the plant Senecio candidans collected in the Chilean Magallanes region. The present study confirms the atomic connectivity assigned on the basis of (1)H and (13)C NMR spectroscopy, as well as the relative stereochemistry of the 4α-methyl,5α-methyl,8β-hydr-oxy,10β-H unit. The crystal structure is stabilized by inter-molecular O-H⋯O hydrogen bonds involving the hydr-oxy group as donor and the oxo group as acceptor, giving chains along the a axis. The absolute structure was not determined because of the lack of suitable anomalous scatters.
منابع مشابه
مروری بر زنبورهای گالزای بلوط در ایران، دامنه میزبانی و برنامه مدیریتی برای حفاظت آنها
فون زنبورهای گالزای ایران که طی سال های 1380-1386 از روی 6 گونه بلوط در جنگل های بلوط کشور جمع آوری شده است در این مقاله مرور شده است. در این بررسی ها 78 گونه زنبور گالزا جمع آوری و شناسایی گردیده که 18 گونه از آنها برای دنیای علم توصیف گردیده و 20 گونه نیز برای اولین بار از کشور گزارش گردید. اهمیت این زنبورها و برنامه مدیریتی برای حفاظت از آنها مورد بحث قرار گرفته است . اسامی علمی زنبورهای گال...
متن کاملA note on $lambda$-Aluthge transforms of operators
Let $A=U|A|$ be the polar decomposition of an operator $A$ on a Hilbert space $mathscr{H}$ and $lambdain(0,1)$. The $lambda$-Aluthge transform of $A$ is defined by $tilde{A}_lambda:=|A|^lambda U|A|^{1-lambda}$. In this paper we show that emph{i}) when $mathscr{N}(|A|)=0$, $A$ is self-adjoint if and only if so is $tilde{A}_lambda$ for some $lambdaneq{1over2}$. Also $A$ is self adjoint if and onl...
متن کاملGeneralized sigma-derivation on Banach algebras
Let $mathcal{A}$ be a Banach algebra and $mathcal{M}$ be a Banach $mathcal{A}$-bimodule. We say that a linear mapping $delta:mathcal{A} rightarrow mathcal{M}$ is a generalized $sigma$-derivation whenever there exists a $sigma$-derivation $d:mathcal{A} rightarrow mathcal{M}$ such that $delta(ab) = delta(a)sigma(b) + sigma(a)d(b)$, for all $a,b in mathcal{A}$. Giving some facts concerning general...
متن کاملHigh-Resolution HLA-A Typing in Normal Iranian Population
Background: Human leukocyte antigen (HLA) gene is a highly polymorphic region. HLA typing is required to match patients and donors for transplantation; therefore, development of HLA registries is necessary for finding HLA match donors. HLA system is highly informative, and numerous studies have been conducted on HLA allele distribution in different populations. Methods: In this study,...
متن کاملAmitraz Poisoning; A case study
A m i t r a z, a n i ns e c t i c i d e /a ca ri c i de of the f o r m a m i d i n e p e st i c i d e s group, is a ? 2 a d r e n e r g i c ag on i st a nd of t he a m i d i ne c h e m i ca l f a m il y generally us e d to c o n t r ol animal e c top a r a s i t e s. Poisoning due to am i t r a z i s r a r e and character...
متن کامل